William H Brendley

45158355, May 7, 1985

Dec 23, 1982

6/452546

Robert R. Kuhn - Lansdale PA
John D. Whiteman - Churchville PA
William H. Brendley - Hatboro PA

Rohm and Haas Company - Philadelphia PA

B05D 716
C08L 6128

4273883

Disclosed herein are high solids thermosetting compositions comprising a solution of a soft, low molecular weight, hydroxy-functional addition polymer resin and a low molecular weight reactive diluent having two or three aliphatic hydroxyl groups per molecule, the weight ratio of resin to diluent being greater than 1, said coating composition when combined with melamine crosslinking agent being of sprayable, roller coatable, or dip coatable viscosity. Cured coatings, coated articles and processes of coating an article are also disclosed.

39621677, Jun 8, 1976

Nov 27, 1974

5/527792

Richard Martorano - Marlton NJ
William H. Brendley - Hatboro PA
Thomas H. Haag - Feasterville PA

Rohm and Haas Company - Philadelphia PA

C08L 6120

260 294UA

Aqueous resinous compositions having an alkaline pH for application to metal sheets and curing the same prior to shaping the metals to achieve metal decoration are disclosed. By "decorating" is meant applying synthetic resinous coatings to the metal followed by a severe mechanical forming operation such as the formation of screw-threaded bottle caps. The composition is thermosettable and comprises (A) an addition copolymer of certain monomers and (B) a water-soluble urea-formaldehyde reaction product or a water-soluble methanol or ethanol ether thereof. The copolymer contains small amounts of carboxyl and amide and/or hydroxyl functionality. The weight ratio of (A) to (B) is from 35:65 to 65:35, and the solids content is between 40 and 80 percent. The coating composition has properties which similar previously known aqueous compositions lack, an important one being that the composition may be direct-roller coated onto the substrate without fouling the coating roller with a partially dried accumulation of the coating composition. The coated panels having a wet coating may be placed directly into the curing oven without blistering, avoiding the necessity of a preliminary low temperature drying step and freedom from patterning.

54037980, Apr 4, 1995

Sep 3, 1992

7/938769

William H. Brendley - Hatboro PA
Russell S. Drago - Gainsville FL
Krzysztof Jurczyk - Gainsville FL

Rohm and Haas Company - Philadelphia PA

B01J 802
B01D 5336

502 38

A method for oxidizing hydrocarbon compounds comprising passing a mixture of the hydrocarbon compound and excess oxygen over a catalyst comprising a carbonaceous substrate doped with a compound selected from the group consisting of metal oxide, metal oxyhalide, and precursors which form metal oxide and metal oxyhalide, and blends thereof under mild reaction conditions. The temperature of the reaction is below about 300. degree. C.

42860210, Aug 25, 1981

May 16, 1975

5/578289

William H. Brendley - Hatboro PA

Rohm and Haas Company - Philadelphia PA

B05D 104
B05D 106
B05D 302

428413

Low molecular weight copolymers of (1) acrylic acid esters or methacrylic acid esters of alcohols such as methanol with (2) esters of bicyclic alcohols such as isobornyl alcohol and unsaturated acids such as methacrylic acid, as contrasted with high molecular weight copolymers of such monomers (1) and (2) (see U. S. Pat. No. 3,485,775) and as contrasted to other acrylic polymers, are found to be exceptional in compatibility with practically all types of hard coating resins, and to lower the flow temperature of the mixture when using powder coating methods such as an electrostatic spray or a fluidized bed, electrostatic or not, as compared with the use of the hard coating resin alone.

40202194, Apr 26, 1977

Nov 27, 1974

5/527791

Richard Martorano - Marlton NJ
William H. Brendley - Hatboro PA
Thomas H. Haag - Feasterville PA

Rohm and Haas Company - Philadelphia PA

B32B 1508
B21C 2322

428460

Aqueous resinous compositions having an alkaline pH for application to metal sheets and curing the same prior to shaping the metals to achieve metal decoration are disclosed. By "decorating" is meant applying synthetic resinous coatings to the metal followed by a severe mechanical forming operation such as the formation of screw-threaded bottle caps. The composition is thermosettable and comprises (A) an addition copolymer of certain monomers and (B) a water-soluble urea-formaldehyde reaction product or a water-soluble methanor or ethanol ether thereof. The copolymer contains small amounts of carboxyl and amide and/or hydroxyl functionality. The weight ratio of (A) to (B) is from 35:65 to 65:35, and the solids content is between 40 and 80 percent. The coating composition has properties which similar previously known aqueous compositions lack, an important one being that the composition may be direct-roller coated onto the substrate without fouling the coating roller with a partially dried accumulation of the coating composition. The coated panels having a wet coating may be placed directly in the curing oven without blistering, avoiding the necessity of a preliminary low temperature drying step and freedom from patterning.

41315723, Dec 26, 1978

May 16, 1975

5/578441

William H. Brendley - Hatboro PA

Rohm and Haas Company - Philadelphia PA

C08L 110

260 17R

Low molecular weight copolymers of (1) acrylic acid esters or methacrylic acid esters of alcohols such as methanol with (2) esters of bicyclic alcohols such as isobornyl alcohol and unsaturated acids such as methacrylic acid, as contrasted with high molecular weight copolymers of such monomers (1) and (2) (see U. S. patent No. 3,485,775) and as contrasted to other acrylic polymers, are found to be exceptional in compatibility with practically all types of hard coating resins, and to lower the flow temperature of the mixture when using powder coating methods such as an electrostatic spray or a fluidized bed, electrostatic or not, as compared with the use of the hard coating resin alone.

53446305, Sep 6, 1994

Jun 28, 1991

7/721763

William H. Brendley - Hatboro PA
Gerald Grunewald - Orange TX
Steven Petrosius - Gainesville FL
Russell Drago - Gainesville FL

Rohm and Haas Company - Philadelphia PA

B01J 802
C01B 701

423240R

A method for oxidizing halogenated organic compounds comprising passing a mixture of the halogenated organic compound and excess oxygen over a catalyst comprising a carbonaceous material under mild reaction conditions. The temperature of the reaction is below 400. degree. C. and the catalyst may be doped with acidic redox-active metal compounds.

41906934, Feb 26, 1980

May 15, 1978

5/905904

Richard Martorano - Marlton NJ
William H. Brendley - Hatboro PA

Rohm and Haas Company - Philadelphia PA

B32B 1508
B05D 128

428209

This invention discloses stable water-based thermosettable coating compositions particularly adapted for the direct roll coating of substrates. The composition comprises (1) an aqueous solution or colloidal solution of a volatile amine or ammonia salt of a high molecular weight carboxylic acid-containing acrylic copolymer, (2) a carboxylic acid-containing acrylic oligomer in the solution, and (3) an aqueous dispersion or solution of a crosslinker; the volatile aqueous phase being by volume 70 to 95% water and 5 to 30% organic solvents, the solids content 15 to 70% by weight and the viscosity between 25 and 150 seconds measured in the number 4 Ford cup.