Inventors:
Tsoung Y. Yan - Philadelphia PA, 19130
Jen-Ray Chang - Chia-Yi, TW
International Classification:
C07C 6902
Abstract:
Aliphatic esters, RCOOR are produced by reacting the corresponding alcohol, ROH having carbon numbers of the alkyl groups, Râ and R, between 0 and 9 and 1 and 10, respectively, with molecular oxygen in the presence of a dual functional catalyst comprising metal on acidic solid support. In particular, the process is used advantageously for production of ethyl acetate by conversion of ethanol. The reaction mixture from the reactor is separated through azeotropic distillation to recover the ethyl acetate as product and the by-product, acetaldehyde and acetic acid which could be recycled for further reaction. The process is characterized by high conversion of ethanol, high selectivity and high yield for ethyl acetate and low waste stream generation. The preferred catalyst is Pd on zeolites which is active, selective, stable and regenerable.