Inventors:
Joy Cheng - San Jose CA, US
Matthew E. Colburn - Schenectady NY, US
Stefan Harrer - New York City NY, US
William D. Hinsberg - Fremont CA, US
Steven J. Holmes - Guilderland NY, US
Daniel Paul Sanders - San Jose CA, US
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
B81C 1/00
C08J 5/18
C08J 5/00
US Classification:
427259, 427256, 427258, 427261, 427264, 427265, 427270, 427271, 427272, 427282, 427 58, 427 961, 427 971, 427 984, 430311, 430312, 430313, 430322, 430325
Abstract:
A layered structure comprising a self-assembled material is formed by a method that includes forming a photochemically, thermally and/or chemically treated patterned photoresist layer disposed on a first surface of a substrate. The treated patterned photoresist layer comprises a non-crosslinked treated photoresist. An orientation control material is cast on the treated patterned photoresist layer, forming a layer containing orientation control material bound to a second surface of the substrate. The treated photoresist and, optionally, any non-bound orientation control material are removed by a development process, resulting in a pre-pattern for self-assembly. A material capable of self-assembly is cast on the pre-pattern. The casted material is allowed to self-assemble with optional heating and/or annealing to produce the layered structure.