Inventors:
Craig R. Metzner - Fremont CA, US
Shreyas S. Kher - Campbell CA, US
Shixue Han - Milpitas CA, US
Assignee:
Applied Materials, Inc. - Santa Clara CA
International Classification:
H01L021/31
Abstract:
A method of forming a dielectric stack on a pre-treated surface. The method comprises pre-cleaning a semiconductor wafer to remove native oxide, such as by applying hydroflouric acid to form an HF-last surface, pre-treating the HF-last surface with ozonated deionized water, forming a dielectric stack on the pre-treated surface and providing a flow of NHin a process zone surrounding the wafer. Alternately, the method includes pre-treating the HF-last surface with NH, forming the stack after the pre-treating, and providing a flow of Nin a process zone surrounding the wafer after the forming. The method also includes pre-treating the HF-last surface using an in-situ steam generation process, forming the stack on the pre-treated surface, and annealing the wafer after the forming. The pre-treating includes providing an inert gas flow in a process zone surrounding the HF-last surface, reacting hydrogen with an oxidizer in the process zone for a very short duration, and providing an inert gas flew in the process zone after the reacting.