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Richard Eibeck Phones & Addresses

  • 3400 Wagner Heights Rd APT 303, Stockton, CA 95209
  • 14 Tanager Ln, Sedona, AZ 86336 (928) 203-0219
  • 900 Cliff Rose Ct, Sedona, AZ 86336 (928) 203-0227
  • Orchard Park, NY
  • Redwood City, CA
  • Flagstaff, AZ

Publications

Us Patents

Production Of Sulfuryl Fluoride

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US Patent:
40039846, Jan 18, 1977
Filed:
Oct 2, 1975
Appl. No.:
5/619103
Inventors:
Edward Stephen Jones - Williamsville NY
Martin Alvin Robinson - East Amherst NY
Richard Elmer Eibeck - Orchard Park NY
Assignee:
Allied Chemical Corporation - Morris Township NJ
International Classification:
C01B 1745
US Classification:
423468
Abstract:
Sulfuryl fluoride is produced by reacting a gaseous mixture of chlorine, sulfur dioxide and hydrogen fluoride, at a temperature between about 125. degree. and 400. degree. C in the presence of a catalytic amount of an alkaline earth metal fluoride.

Production Of Perfluoropropane

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US Patent:
43777155, Mar 22, 1983
Filed:
Dec 26, 1979
Appl. No.:
6/107123
Inventors:
Henry R. Nychka - East Aurora NY
John B. Hino - Cheektowaga NY
Richard E. Eibeck - Orchard Park NY
Martin A. Robinson - East Amherst NY
Assignee:
Allied Corporation - Morristown NJ
International Classification:
C07C 1702
US Classification:
570123
Abstract:
Octafluoropropane or perfluoropropane is produced by introducing fluorine into an elongated inner zone surrounded by a porous member which is substantially resistant to fluorine corrosion and introducing a three carbon compound which is propane, a partially fluorinated propane, propene, a partially fluorinated propene, hexafluoropropene or mixtures thereof outside the porous member. When the porous member is metal, a perfluorinated diluent is used. When the porous member is fused alumina, conventional diluents such as nitrogen, or even no diluent may be employed.

Recyclable Boron Trifluoride Catalyst And Method Of Using Same

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US Patent:
42270278, Oct 7, 1980
Filed:
Nov 23, 1979
Appl. No.:
6/096955
Inventors:
Robert E. Booth - Hamburg NY
Francis E. Evans - Hamburg NY
Richard E. Eibeck - Orchard Park NY
Martin A. Robinson - Amherst NY
Assignee:
Allied Chemical Corporation - Morris Township, Morris County NJ
International Classification:
C07C 356
C07C 318
US Classification:
585465
Abstract:
When saturated with boron trifluoride, certain polyhydric alcohols form adducts which catalyze hydrocarbon alkyl transfer reactions for which boron trifluoride is catalytic. The adduct is recovered from the reaction mixture and recycled, greatly reducing boron and fluoride values in the product and in any effluent. Examples include propylation of toluene in the presence of a recycled adduct of boron trifluoride with mannitol or sorbitol, and the oligomerization of decene by a recycled adduct of boron trifluoride with mannitol or butanediol. Some of the catalysts become viscous on cooling and are thus more easily separated from the reaction products which remain in a separate liquid phase.

Process For The Preparation Of Perhaloalkanoyl Chloride

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US Patent:
43405487, Jul 20, 1982
Filed:
Dec 15, 1980
Appl. No.:
6/216033
Inventors:
Louis G. Anello - Hamburg NY
Richard E. Eibeck - Orchard Park NY
Martin A. Robinson - East Amherst NY
Assignee:
Allied Corporation - Morris Township, Morris County NJ
International Classification:
C07C 5158
US Classification:
260544Y
Abstract:
A process for the preparation of perhaloalkanoyl chloride is disclosed which comprises reacting 1,1,1-trichloroperfluoroalkane, with a sulfur trioxide-containing compound selected from the group consisting of oleum sulfur trioxide and stabilized sulfur trioxide in the presence of catalytic amounts of a halogen catalyst selected from the group consisting of iodine, bromine, iodine monobromide and iodine monochloride and bromine monochloride. The preferred product is trifluoroacetyl chloride.

Preparation Of Fluoroorganic Compounds With Calcium Fluoride

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US Patent:
41743490, Nov 13, 1979
Filed:
Oct 30, 1978
Appl. No.:
5/955679
Inventors:
Francis E. Evans - Hamburg NY
Morris B. Berenbaum - Summit NJ
Richard E. Eibeck - Orchard Park NY
Martin A. Robinson - East Amherst NY
Assignee:
Allied Chemical Corporation - Morris Township, Morris County NJ
International Classification:
C07C 1710
C07C 1712
C07C 1714
C07C 5158
US Classification:
260544F
Abstract:
Fluoroorganic compounds are prepared by reacting a haloorganic starting material in which at least one halo atom is replaceable with a fluorine atom by metathetical exchange, with calcium fluoride in the presence of a crown ether and an anhydrous, polar, basic organic solvent which complexes with the calcium ion and contains no --OH groups, at a temperature and for a period of time adequate to effect fluorination.

Production Of Fluorocarbons Employing Two Catalyst Zones

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US Patent:
40887049, May 9, 1978
Filed:
Jan 21, 1977
Appl. No.:
5/761161
Inventors:
Henry R. Nychka - E. Aurora NY
Richard E. Eibeck - Orchard Park NY
Assignee:
Allied Chemical Corporation - Morris Township, Morris County NJ
International Classification:
C07C 1710
US Classification:
260653
Abstract:
Highly chlorinated hydrocarbons having one to three carbons such as CCl. sub. 4, C. sub. 2 Cl. sub. 6 and C. sub. 3 Cl. sub. 8 are reacted with HF in the presence of a fluorination catalyst such as gamma aluminum fluoride. The effluent is reacted with unhalogenated or underhalogenated hydrocarbons having 1 to 3 carbons, such as CH. sub. 4, CH. sub. 3 Cl, C. sub. 2 H. sub. 5 Cl, C. sub. 2 H. sub. 6, CH. sub. 2. dbd. CHCl and CFCl. dbd. CCl. sub. 2, and O. sub. 2 in the presence of an oxychlorination catalyst, such as cupric chloride with alkali halide or alkaline earth halide promoters on alpha aluminum fluoride. Fluorocarbons having 1 to 3 carbons such as CCl. sub. 2 F. sub. 2, C. sub. 2 Cl. sub. 3 F. sub. 3 and C. sub. 2 Cl. sub. 2 F. sub. 4 are separated from the effluent. Preferably, highly chlorinated materials are recycled onto the fluorination catalyst and underhalogenated materials are recycled onto the oxychlorination catalyst.

Process For The Preparation Of Fluorinated Alkanes From Alkenes

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US Patent:
49373986, Jun 26, 1990
Filed:
Dec 27, 1988
Appl. No.:
7/290129
Inventors:
Hsueh S. Tung - Williamsville NY
Richard E. Eibeck - Orchard Park NY
Bernard Sukornick - Williamsville NY
Assignee:
Allied-Signal Inc. - Morris Township, Morris County NJ
International Classification:
C07C 1702
C07C 1704
C07C 1902
C07C 1706
US Classification:
570175
Abstract:
The present invention provides a process for the preparation of luorinated alkanes. The process comprises the step of: reacting an alkene with carbon having fluorine absorbed therein at a temperature and for a time sufficient to form fluorinated alkanes. The alkene used is not perhalogenated at the double-bonded carbons. Preferably, the alkene used is vinylidene fluoride or ethylene. The process produces products such as 1,1,1,2-tetrafluoroethane (known in the art as 134a) which may be used as a refrigerant and 1,1,1-trifluoroethane (known in the art as R143a) and 1,2-difluoroethane (known in the art as R152) which may be used as blowing agents or solvents.

Recyclable Boron Trifluoride Catalyst And Method Of Using Same

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US Patent:
42096545, Jun 24, 1980
Filed:
Oct 16, 1978
Appl. No.:
5/951911
Inventors:
Robert E. Booth - Hamburg NY
Francis E. Evans - Hamburg NY
Richard E. Eibeck - Orchard Park NY
Martin A. Robinson - East Amherst NY
Assignee:
Allied Chemical Corporation - Morris Township NJ
International Classification:
C07C 356
C07C 318
US Classification:
585465
Abstract:
When saturated with boron trifluoride, certain polyhydric alcohols form adducts which catalyze reactions for which boron trifluoride is catalytic. The adduct is recovered from the reaction mixture and recycled, greatly reducing boron and fluoride values in the product and in any effluent. Examples include propylation of toluene in the presence of a recycled adduct of boron trifluoride with mannitol or sorbitol.
Richard E Eibeck from Stockton, CA, age ~89 Get Report