Inventors:
David M. Dean - West Chester PA
Richard James Arhart - Wilmington DE
Assignee:
E. I. du Pont de Nemours and Company - Wilmington DE
International Classification:
D02G 300
US Classification:
428379, 428383, 428389, 174110 SR, 174110 PM, 525 92, 525212
Abstract:
The present invention relates an electrically conductive wire having a metal core and an outer electrically-insulative, polymer coating wherein the polymer composition contains polyphenylene sulfide, a polymeric grafting agent and an ethylene copolymer. The polymeric grafting agent is a copolymer of at least about 50% by weight ethylene, about 0. 5% to about 15% by weight of a reactive comonomer selected from the group consisting of: (i) an unsaturated epoxide of 4-11 carbon atoms, (ii) an unsaturated isocyanate of 2-11 carbon atoms, (iii) an unsaturated alkoxy silane and/or unsaturated alkyl silane wherein the alkoxy or alkyl group is from 1-12 carbon atoms, and (iv) an oxazoline; and about 0 to about 49% by weight of a third optional comonomer selected from at least one of an alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, where the alkyl and ether groups are of 1-12 carbon atoms. The ethylene copolymer comprises at least about 50% by weight ethylene, about 1% to about 35% by weight of an acid-containing unsaturated mono-carboxylic acid, and about 0 to about 49% by weight of a moiety selected from at least one of alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, and further wherein the acid groups are neutralized from 0-100% by a metal ion. Such wire meets SAE J1678 specifications at 125Â C.