Inventors:
Masakazu Hasegawa - Hachioji, JP
Michael P. Keyes - Minneapolis MN
Marc D. Radcliffe - Newport MN
Patricia M. Savu - Maplewood MN
Daniel C. Snustad - Woodbury MN
Terence D. Spawn - West Lakeland Township MN
Assignee:
3M Innovative Properties Company - St. Paul MN
International Classification:
C09K 1934
C09K 1932
C07C 2513
C07D23902
C07D31912
C07D26302
Abstract:
Fluorine-containing, chiral liquid crystal compounds comprise (a) a chiral fluorochemical terminal portion comprising (i) at least one chiral center, which can optionally be heteroatom-substituted; (ii) a terminal fluoroalkyl, fluoroether, perfluoroalkyl, or perfluoroether group; and (iii) an alkylene or fluoroalkylene group optionally containing at least one caternary ether oxygen atom; (b) a chiral or achiral terminal portion consisting of a hydrocarbon or hydrocarbon ether group, and, when chiral, comprising at least one chiral center, which can optionally be heteroatom-substituted; and (c) a central core connecting the terminal portions; the alkylene or fluoroalkylene group of the chiral fluorochemical terminal portion having at least 3 in-chain atoms and being located between the chiral center of the chiral fluorochemical terminal portion and the central core. The compounds have smectic mesophases or latent smectic mesophases and are useful, for example, in liquid crystal display devices.