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Nicolay Tsarevsky Phones & Addresses

  • 8319 Crystalwood Dr, Dallas, TX 75249
  • 5628 Forbes Ave, Pittsburgh, PA 15217 (412) 422-5469

Work

Company: Southern methodist university Jun 2010 Position: Assistant professor of chemistry

Education

Degree: Ph.D. School / High School: Carnegie Mellon University 2000 to 2005 Specialities: Chemistry

Skills

Chemistry • Materials Science • Polymers • Polymer Chemistry • Science • Spectroscopy • Organic Chemistry • Nmr • Catalysis • Characterization • Uv/Vis • Surface Chemistry • Hplc • Polymer Characterization • Nanomaterials • Organic Synthesis • Microscopy • Analytical Chemistry • Polymer Science • Nanoparticles • Afm • Ir • Mass Spectrometry • Ftir • Protein Chemistry • Inorganic Chemistry • High Performance Liquid Chromatography • Scanning Electron Microscopy • Higher Education • Uv/Vis Spectroscopy • Nuclear Magnetic Resonance • History of Chemistry • Infrared • History of Science

Languages

English • Russian • Bulgarian • Italian

Interests

Functional Polymers • Education • Opera • Catalysis • Materials Science • History • Hypervalent Iodine

Industries

Higher Education

Resumes

Resumes

Nicolay Tsarevsky Photo 1

Program Chair

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Location:
Dallas, TX
Industry:
Higher Education
Work:
Southern Methodist University since Jun 2010
Assistant Professor of Chemistry

American Chemical Society Jan 2010 - Dec 2010
Immediate Past Chair

ATRP Solutions, Inc. Oct 2007 - Apr 2010
Chief Science Officer

American Chemical Society, Pittsburgh Section Jan 2009 - Jan 2010
Chair

American Chemical Society, Pttsburgh Section Jan 2008 - Jan 2009
Chair-elect
Education:
Carnegie Mellon University 2000 - 2005
Ph.D., Chemistry
Sofia University St. Kliment Ohridski 1994 - 1999
M.S., Theoretical Chemistry and Chemical Physics
Skills:
Chemistry
Materials Science
Polymers
Polymer Chemistry
Science
Spectroscopy
Organic Chemistry
Nmr
Catalysis
Characterization
Uv/Vis
Surface Chemistry
Hplc
Polymer Characterization
Nanomaterials
Organic Synthesis
Microscopy
Analytical Chemistry
Polymer Science
Nanoparticles
Afm
Ir
Mass Spectrometry
Ftir
Protein Chemistry
Inorganic Chemistry
High Performance Liquid Chromatography
Scanning Electron Microscopy
Higher Education
Uv/Vis Spectroscopy
Nuclear Magnetic Resonance
History of Chemistry
Infrared
History of Science
Interests:
Functional Polymers
Education
Opera
Catalysis
Materials Science
History
Hypervalent Iodine
Languages:
English
Russian
Bulgarian
Italian

Publications

Us Patents

Process For The Preparation Of Nanostructured Materials

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US Patent:
7056455, Jun 6, 2006
Filed:
Apr 6, 2002
Appl. No.:
10/118519
Inventors:
Krzysztof Matyjaszewski - Pittsburgh PA, US
Tomasz Kowalewski - Pittsburgh PA, US
David N. Lambeth - Pittsburgh PA, US
James Spanswick - Wheaton IL, US
Nicolay V. Tsarevsky - Pittsburgh PA, US
Assignee:
Carnegie Mellon University - Pittsburgh PA
International Classification:
D01F 9/12
US Classification:
264 292, 4234471, 521 61, 521 62, 521 63, 521 77, 521918, 521919, 50252724
Abstract:
The present invention comprises a novel process for the preparation of carbon based structured materials with controlled topology, morphology and functionality. The nanostructured materials are prepared by controlled carbonization, or pyrolysis, of precursors comprising phase separated copolymers. The precursor materials are selected to phase separate and self organize in bulk, in solution, in the presence of phase selective solvents, at surfaces, interfaces or during fabrication, into articles, fibers or films exhibiting well-defined, self-organized morphology or precursors of well-defined, self-organized, bi- or tri-phasic morphology. Compositional control over the (co)polymers provides control over the structure of the phase separated precursor whose organization therein dictates the nanostructure of the material obtained after carbonization or pyrolysis, wherein each dimension of the formed structure can be predetermined. When the precursor morphology is selected to comprise cylindrical domains this procedure additionally allows for the direct formation of two dimensional nanowire grids or arrays of oriented nanostructures on surfaces. When these nanowire grids or arrays are perpendicularly oriented to the surface applications include field emitters, high surface area electrodes, electronic devices such as diodes and transistors, tools for AMF tips and elements of molecular electronics.

Stabilization Of Transition Metal Complexes For Catalysis In Diverse Environments

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US Patent:
7332550, Feb 19, 2008
Filed:
Oct 10, 2003
Appl. No.:
10/684137
Inventors:
Krzysztof Matyjaszewski - Pittsburgh PA, US
Nicolay Tsarevsky - Pittsburgh PA, US
Assignee:
Carnegie Mellon University - Pittsburgh PA
International Classification:
C08F 20/06
C08F 20/04
C08F 4/44
C08F 4/72
US Classification:
526 91, 526 90, 526 93, 526 94, 526172, 5263171
Abstract:
This present invention is directed towards the identification or design, preparation, and use of suitable transition metal complexes for use as catalysts. The transition metal complexes may comprise heterodonor ligands. The present invention is also directed toward a method of determining the suitability of a transition metal complex for use in a catalytic reaction, such as, but not limited to, atom transfer radical polymerization (“ATRP”), atom transfer radical addition (“ATRA”), atom transfer radical cyclization (“ATRC”), and other catalytic redox reactions. The method assists in the approximate determination of the fundamental properties of the transition metal complex in a reaction media, such as, but not limited to, solubility, redox potential, stability towards acidic, basic, or ionic species, conditional radically transferable atom phylicity, and propensity toward disproportionation and therefore, the suitability of the complex to be used as a catalyst in the reaction media. The method provides a basis for prediction and evaluation of the properties of a transition metal complex for a particular selective catalytic reaction in a broad range of reaction environments. An understanding of the principles of the disclosed method allows a transition metal complex to be tuned to specific reaction medium by selecting a transition metal complex and ligand combination having the desired qualities.

Preparation Of Functional Polymers

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US Patent:
7795355, Sep 14, 2010
Filed:
Mar 7, 2005
Appl. No.:
10/591425
Inventors:
Krzyszlof Matyjaszewski - Pittsburgh PA, US
Brent S. Sumerlin - Pittsburgh PA, US
Nicolay V. Tsarevsky - Pittsburgh PA, US
James Spanswick - Wheaton IL, US
Assignee:
Carnegie Mellon University - Pittsburgh PA
International Classification:
C08F 8/30
US Classification:
5253282, 5253283, 5253291, 5253292, 5253293, 525376
Abstract:
The process of the present invention is directed toward conducting highly selective, high yield post polymerization reactions on polymers to prepare functionalized polymers. An embodiment of the present invention comprises conducting click chemistry reactions on polymers. Preferably, the polymers were prepared by controlled polymerization processes. Therefore, embodiments of the present invention comprise processes for the preparation of polymers comprising conducting a click chemistry reaction on a functional group attached to a polymer, wherein the polymer has a molecular weight distribution of less than 2. The functional polymers may be prepared by converting an attached functional unit on the polymer thereby providing site specific functional materials, site specific functional materials comprising additional functionality, or chain extended functional materials. Embodiments of the process of the present invention include functionalization reactions, chain extensions reactions, to form mock copolymer linking reactions, and attaching side chains to form graft copolymers, for example.

Atom Transfer Radical Polymerization Process

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US Patent:
7893174, Feb 22, 2011
Filed:
Mar 7, 2005
Appl. No.:
10/591426
Inventors:
Krzysztof Matyjaszewski - Pittsburgh PA, US
Lindsay Bombalski - Pittsburgh PA, US
Wojciech Jakubowski - Pittsburgh PA, US
Ke Min - Pittsburgh PA, US
James Spanswick - Wheaton IL, US
Nicolay V. Tsarevsky - Pittsburgh PA, US
Assignee:
Carnegie Mellon University - Pittsburgh PA
International Classification:
C08F 4/40
US Classification:
526111, 526 96, 526135, 526145, 526146, 526147, 525168, 525243, 525245, 525247
Abstract:
Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprise reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.

Star Macromolecules For Personal And Home Care

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US Patent:
8173750, May 8, 2012
Filed:
Oct 27, 2010
Appl. No.:
12/926143
Inventors:
Wojciech Jakubowski - Pittsburgh PA, US
Patrick McCarthy - Pittsburgh PA, US
Nicolay Tsarevsky - Dallas TX, US
James Spanswick - Pittsburgh PA, US
Assignee:
ATRP Solutions, Inc. - Pittsburgh PA
International Classification:
C08F 287/00
C08F 285/00
US Classification:
525244, 525 50, 525 70, 525191, 525193, 525241, 525301, 525221, 525227, 525223
Abstract:
A polymer composition comprising star macromolecules is provided. Each star macromolecule has a core and five or more arms, wherein the number of arms within a star macromolecule varies across the composition of star molecules. The arms on a star are covalently attached to the core of the star; each arm comprises one or more (co)polymer segments; and at least one arm and/or at least one segment exhibits a different solubility from at least one other arm or one other segment, respectively, in a reference liquid of interest.

Modification Of Surfaces With Polymers

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US Patent:
8349410, Jan 8, 2013
Filed:
Aug 17, 2007
Appl. No.:
11/894010
Inventors:
Jinyu Huang - Duluth GA, US
Alan J. Russell - Gibsonia PA, US
Nicolay V. Tsarevsky - Pittsburgh PA, US
Krzysztof Matyjaszewski - Pittsburgh PA, US
Assignee:
University of Pittsburgh—of the Commonwealth System of Higher Education - Pittsburgh PA
Carnegie Mellon University - Pittsburgh PA
International Classification:
C09D 5/14
C08F 2/46
C08J 7/14
C08F 8/02
C08F 220/34
US Classification:
427508, 427510, 522 46, 523122, 525383, 526287, 526311
Abstract:
A polymer formed by controlled radical polymerization includes groups that can be modified after controlled radical polymerization to form a radical. The polymer can be the reaction product of a controlled radical polymerization of radically polymerizable monomers, wherein at least one of the radically polymerizable monomers includes at least one group that can be modified after the controlled radical polymerization to form a radical. A compound includes a first group that is stimulated upon application of energy to the molecule to tether the molecule to a surface or to another polymer chain and a second group comprising a controlled radical polymerization initiator functionality. A block copolymer includes at least a first segment to impart a predetermined functionality to a target surface and at least a second segment including functional groups to interact with the targeted surface to attach the block copolymer to the surface. The first segment can free of functional groups that interact with the surface to attach the block copolymer to the surface.

Preparation Of Functional Gel Particles With A Dual Crosslink Network

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US Patent:
8367051, Feb 5, 2013
Filed:
Oct 9, 2007
Appl. No.:
12/311673
Inventors:
Krzysztof Matyjaszewski - Pittsburgh PA, US
Ke Min - Albany CA, US
Jung Kwon Oh - Midland MI, US
James Spanswick - Wheaton IL, US
Nicolay V. Tsarevsky - Pittsburgh PA, US
Assignee:
Carnegie Mellon University - Pittsburgh PA
International Classification:
A61K 9/14
A61K 31/74
US Classification:
424 7831, 424489
Abstract:
Functional gel particle formed from a crosslinked polymeric network including a fraction of stable crosslinks and a second fraction of cleavable crosslinks are disclosed. Functional compounds may be chemically or physically encapsulated within and/or released from the gel particle by selective cleavage of the cleavable crosslinks. The functional compounds may be delivered and released to a pre-selected target site. Peripheral or other accessible functionality on the surface of the gel particle allows attachment of a surface reactive agent, thereby modifying one or more surface properties of the gel particle. Processes of preparing the gel particles and processes of delivering the functional compounds to a target site are also disclosed.

Atom Transfer Radical Polymerization Process

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US Patent:
8404788, Mar 26, 2013
Filed:
Feb 14, 2011
Appl. No.:
13/026919
Inventors:
Krzysztof Matyjaszewski - Pittsburgh PA, US
Lindsay Bombalski - Pittsburgh PA, US
Wojciech Jakubowski - Pittsburgh PA, US
Ke Min - Pittsburgh PA, US
Nicolay V. Tsarevsky - Pittsburgh PA, US
James Spanswick - Wheaton IL, US
Assignee:
Carnegie Mellon University - Pittsburgh PA
International Classification:
C08F 4/40
US Classification:
526111, 526 96, 526135, 526145, 526146, 526147, 525168, 525243, 525245, 525247
Abstract:
Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
Nicolay V Tsarevsky from Dallas, TX, age ~48 Get Report