Inventors:
Eric Hunter Shreiber - Getzville NY
Edward Paul Eardley - Lockport NY
Vijayaraghavan Srinivasan - Williamsville NY
Bart Antonie van Hassel - Getzville NY
Minish Mahendra Shah - East Amherst NY
Assignee:
Praxair Technology, Inc. - Danbury CT
International Classification:
B01D 5322
US Classification:
423219, 60 3912, 60772, 60774, 60801, 95 45, 95 54, 95288
Abstract:
A method of separating oxygen using a ceramic membrane unit having one or more ceramic membranes, preferably formed of a mixed conducting ceramic, for instance, a perovskite, capable of conducting both oxygen ions and electrons. Oxygen is separated within the ceramic membrane unit under impetus of compressing an incoming oxygen containing feed. The compressor used in the compression is powered by the work of expansion produced by expanding a process stream composed of at least a portion of the retentate produced in the ceramic membrane unit. Prior to expansion, the process stream is cooled to allow the use of less expensive materials in expanders used in the expansion. As a result, expansion of the process stream alone is insufficient to meet the power requirements involved in the compression. Interstage expansion with reheating is used to make up for the power deficit.