Inventors:
Edwin J. Bielecki - Boyertown PA
Karl A. Romberger - Gilbertsville PA
Bart F. Bakke - Douglassville PA
Martin A. Hobin - Allentown PA
Charles R. Clark - Pottstown PA
International Classification:
B01D 1100
Abstract:
A metallurgical processing system for economically recovering metal values, such as columbium, tantalum, thorium, and uranium from dilute source solids, such as digestion sludges, by a series of steps including: 1) slurrying the source solids with dilute hydrofluoric acid to produce a solid phase and a liquid phase containing dissolved tantalum and columbium, then extracting tantalum and/or columbium from the liquid phase by means of a liquid ion-exchange process and then, additionally; 2) roasting the solid phase with sulfuric acid to recover and recycle hydrofluoric acid, leaching the roasted solids with dilute sulfuric acid to produce a disposable solid phase and a liquid phase containing thorium and uranium, and extracting thorium and uranium from the liquid phase by means of a liquid-liquid amine extraction process.