Inventors:
Krishnakumar Jambunathan - Breinigsville PA, US
Kerry Renard Berger - Lehighton PA, US
Reinaldo Mario Machado - Allentown PA, US
Daniel James Ragsdale - Coopersburg PA, US
Assignee:
Air Products and Chemicals, Inc. - Allentown PA
International Classification:
C22B 9/00
Abstract:
The invention relates to the electrolysis of aqueous electrolyte solutions containing GeO; hydroxide and water with metal alloy electrodes, such as, copper or tin rich alloy electrodes with alloying elements such as Sn, Pb, Zn, Cu etc, to generate Germane (GeH). Cu-rich alloy electrodes have been demonstrated to increase the GeHcurrent efficiency by almost 20% compared to Cu metal electrodes. Germanium deposition has been found to be either absent or minimal by using Cu-rich alloy electrodes. Several different methods for maintaining the cell performance or restoring the cell performance after a reduction in current efficiency over time, have been identified. A titration-based method for the analysis of the electrolyte, to obtain the concentration of GeOand the concentration of hydroxide has also been disclosed.