US Patent:
20110183840, Jul 28, 2011
Inventors:
John G. DARAB - Flemington NJ, US
Assignee:
MAGNESIUM ELEKTRON LIMITED - Salford Quays
International Classification:
B01J 21/06
B01J 37/03
B01J 37/06
B01J 37/08
B01J 27/055
B01J 27/053
B01J 27/135
US Classification:
502218, 502349, 502217, 502227, 502304, 502303, 502302
Abstract:
An improved method for the formation of composite hydroxides or oxides comprising, on an oxide basis, AlOand ZrO, and optionally CeO, LaO, NdO, PrO, SmO, YO, and other rare earth oxides, comprising the steps of preparing an aqueous metal salt solution and forming a hydroxide precipitate slurry by combining the aqueous metal salt solution with an aqueous solution of a caustic alkali at a pH greater than 8.5 to precipitate out all the metal species. The variation in pH during the precipitation reaction is 1. The invention also relates to composites formed by this method comprising 20-70 wt % AlO, 10-77 wt % ZrO, 0-34 wt % CeOand 0-22 wt % REOs other than CeO, and to composites per se comprising, on an oxide basis, 42-70 wt % AlO, 10-48 wt % ZrO, 2-34 wt % CeOand 0-9 wt % REOs other than CeOand having the following properties after heating to 850 C. over four hours and holding at 850 C. for four hours then allowing to cool to ambient temperature:—a surface area after aging at 950 C. for 2 hours equal to or greater than 60 m/g, and—a surface area after aging at 1100 C. for 2 hours equal to or greater than 30 m/g.