US Patent:
20020110685, Aug 15, 2002
Inventors:
Ikuko Ebihara - St. Paul MN, US
Guy Kallman - Woodbury MN, US
Gregory Gilligan - Hastings MN, US
William Kausch - Cottage Grove MN, US
Brian Williams - White Bear Lake MN, US
Robert Horn - Woodbury MN, US
International Classification:
B32B027/36
US Classification:
428/336000, 428/483000, 428/910000, 264/204000
Abstract:
A tie layer film, comprising an admixture of polyvinyl alcohol and a water dispersible polyester, for bonding a support film to a topcoat layer. The preferred tie layer comprises a sulfopolyester, preferably including terephthalate groups or isophthalate groups. Most preferred are sulfopolyesters produced from ingredients comprising monomers selected from the group consisting of dimethyl 5-sodiosulfoisophthalate, dimethyl terephthalate, dimethyl isophthalate, ethylene glycol, and polycaprolactone diol. Alternatively the support film may be a layered film. In a preferred embodiment, the topcoat layer is formed from the same PVA material as the tie layer and the support film includes at least a portion of the same sulfopolyester as the tie layer. The tie layer is capable of maintaining the bond between the support film and the topcoat layer when heat stretched to a stretch ratio in the range of 2 times to 10 times its original dimension.